Search results for "Cerium compounds"

showing 2 items of 2 documents

Influence of SMSI effect on the catalytic activity of a Pt(1%)/ Ce0.6Zr0.4O2 catalyst: SAXS, XRD, XPS and TPR investigations

2004

Abstract The steady-state activity of NO reduction by C3H6, in lean conditions, was studied on a Pt(1%)/Ce0.6Zr0.4O2 catalyst, in a plug-flow reactor, in the temperature range 100–500 °C. The influence of reductive pre-treatments on the catalytic performance at low temperature (250 °C) was investigated. Enhancement of the activity was found for the catalyst pre-treated in hydrogen at 350 °C as compared to the sample pre-treated in H2 at 800 and 1050 °C. Moreover, transient reactivity tests of NO reduction by hydrogen were also carried out. As previously observed, the sample reduced at 350 °C was the most active catalyst. In both types of reactions the temperature and the nature of pre-treat…

HydrogenProcess Chemistry and TechnologyReducing atmosphereInorganic chemistryAnalytical chemistrychemistry.chemical_elementAtmospheric temperature rangeCatalysisCatalysischemistryTransition metalX-ray photoelectron spectroscopyTemperature-programmed reductionPlatinumCerium compounds Catalysts capacity OSCGeneral Environmental Science
researchProduct

Template electrosyntesis of CeO2 nanotubes

2007

Nanotube arrays of CeO2 were produced in a single step by potentiostatic electrochemical deposition from a non-aqueous electrolyte, using anodic alumina membrane templates. The CeO2 nanotubes showed a polycrystalline structure, and they were assembled in the membrane nanochannels. The nanotubes had somewhat uniform diameters, with an average external value of about 210 nm, and a maximum length of about 60 µm; the latter parameter was controlled by the electrodeposition time. Each single nanotube was found to consist of crystalline grains having a size of about 3 nm. Raman analysis shows that these CeO2 nanotubes are suitable for catalytic applications.

NanotubeMaterials scienceMechanical EngineeringBioengineeringNanotechnologyGeneral ChemistryElectrolyteCerium compoundsElectrocatalysisElectrodepositionGrain size and shapePolycrystalline materialsSynthesis (chemical)ElectrosynthesisElectrochemistrysymbols.namesakeMembraneSettore ING-IND/23 - Chimica Fisica ApplicataChemical engineeringMechanics of MaterialssymbolsGeneral Materials ScienceCrystalliteElectrical and Electronic EngineeringRaman spectroscopyDeposition (law)
researchProduct